| 書目名稱 | Visualization of Hydrogen-Bond Dynamics | | 副標題 | Water-Based Model Sy | | 編輯 | Takashi Kumagai | | 視頻video | http://file.papertrans.cn/984/983866/983866.mp4 | | 概述 | Addresses direct imaging of hydrogen-bond dynamics within water-based model systems assembled on a metal surface by a scanning tunneling microscope.Characterizes the dynamics of individual hydrogen bo | | 叢書名稱 | Springer Theses | | 圖書封面 |  | | 描述 | The hydrogen bond represents an important interaction between molecules, and the dynamics of hydrogen bonds in water create an ever-present question associated with the process of chemical and biological reactions. In spite of numerous studies, the process remains poorly understood at the microscopic level because hydrogen-bond dynamics, such as bond rearrangements and hydrogen/proton transfer reactions, are extremely difficult to probe. Those studies have been carried out by means of spectroscopic methods where the signal stems from the ensemble of a system and the hydrogen-bond dynamics were inferred indirectly. This book addresses the direct imaging of hydrogen-bond dynamics within water-based model systems assembled on a metal surface, using a scanning tunneling microscope (STM). The dynamics of individual hydrogen bonds in water clusters, hydroxyl clusters, and water-hydroxyl complexes are investigated in conjunction with density functional theory. In these model systems, quantum dynamics of hydrogen bonds, such as tunneling and zero-point nuclear motion, are observed in real space. Most notably, hydrogen atom relay reactions, which are frequently invoked across many fields of | | 出版日期 | Book 2012 | | 關鍵詞 | Hydrogen Bond Dynamics; Hydrogen Transfer; Single Molecule Manipulation; Small Water Clusters; Vibration | | 版次 | 1 | | doi | https://doi.org/10.1007/978-4-431-54156-1 | | isbn_softcover | 978-4-431-54735-8 | | isbn_ebook | 978-4-431-54156-1Series ISSN 2190-5053 Series E-ISSN 2190-5061 | | issn_series | 2190-5053 | | copyright | Springer Japan 2012 |
The information of publication is updating
|
|
|Archiver|手機版|小黑屋|
派博傳思國際
( 京公網安備110108008328)
GMT+8, 2025-10-5 23:37
發(fā)表于 2025-3-21 17:23:46
