Titlebook: Surface Enhanced Raman Scattering; Richard K. Chang,Thomas E. Furtak Book 1982 Plenum Press, New York 1982 electron.electron energy loss s

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A Model Including Excitation of Surface Plasmon Polaritonseriments. However, during the last year or so,. a better theoretical picture is emerging which is capable of analyzing experimental data on substrates with well characterized surface profiles. We will present here salient features of such a theoretical model for the surface-enhanced Raman scattering (SERS).

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The “Adatom Model”: How Important Is Atomic Scale Roughness? signal on polarizations, on angles of incidence and emission and any kind of coupling between the adsorbed molecules or between sites is neglected here, because it is not important for the following discussion.

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Coupled Excitation Model and Quantum Test of Image Field Effect limiting case of our model. In view of the physical simplicity and ease of calculation of classical theories based on image fields, such a test is important in deciding how much credence to give such theories, which have been previously intensively studied. and are reviewed by G. C. Schatz in another chapter in this volume.

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Coverage Dependence can be compared with theoretical predictions. Also, in the submonolayer regime, comparisons of the SERS spectra with coverage-dependent bonding behavior can yield information on effects due to chemical bonding.

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ical characterization of the adsorbates and microscopic structure of surfaces and interfaces. Among the most recently de- veloped techniques, and one around which a storm of controversy has developed, is what has now been earmarked as surface enhanced Raman scattering (SERS). Within this phenomenon,

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