Titlebook: Supercritical Fluids; Fundamentals for App Erdogan Kiran,Johanna M. H. Levelt Sengers Book 1994 Springer Science+Business Media Dordrecht 1

協(xié)議

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Thermodynamics and Fluctuation Solution Theory with Some Applications to Systems at Near- or Supercrh discussion is given of standard states for phase equilibria and results for various sets of independent thermodynamic variables such as in the Lewis-Randall, Kirkwood-Buff and McMillan-Mayer systems. Differences with sets of composition variables based on species and groups for systems with “react

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Effects of Critical Fluctuations on the Thermodynamic and Transport Properties of Supercritical Fluiifically, long-range density fluctuations are present in solvents in the critical region. These critical fluctuations not only cause singular behavior of the thermodynamic and transport properties at the critical point, but also affect these properties in a substantial range of temperatures and dens

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Critical Behavior of Fluids: Concepts and Applicationsquently encountered in applications of supercritical fluids, such as supercritical chromatography. Implications for control of experimental variables, and for the molecular simulation of dilute near-critical mixtures are stated. In the applications, emphasis is given to the phase behavior and thermodynamics of supercritical aqueous systems.