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Titlebook: Steric and Stereoelectronic Effects in Organic Chemistry; Veejendra K. Yadav Book 20161st edition Springer Science+Business Media Singapor

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書(shū)目名稱Steric and Stereoelectronic Effects in Organic Chemistry
編輯Veejendra K. Yadav
視頻videohttp://file.papertrans.cn/878/877417/877417.mp4
概述Explains steric and stereoelectronic effects which control reactions.Offers clear visual effects for easy understanding of the stereochemical relationships.Provides lucid explanations to retain clarit
圖書(shū)封面Titlebook: Steric and Stereoelectronic Effects in Organic Chemistry;  Veejendra K. Yadav Book 20161st edition Springer Science+Business Media Singapor
描述.The steric and stereoelectronic effects control the rate and stereochemical outcome of reactions. Hence, a decent understanding of the related concepts is essential for successful synthetic planning. The book attempts to address several important issues related to these concepts in a simplified manner, and is intended for graduate students. It lays stress on the important aspects of steric and stereoelectronic effects and their control on the conformational profile and reactivity features. The book covers the geometrical requirements for reactions at saturated and unsaturated carbons in both cyclic and acyclic systems, and the resultant stereochemical features. The aspect of geometrical flexibility is also covered with a few examples involving intramolecular reactions. It deals with the facial selectivity of nucleophilic additions to acyclic and cyclic carbonyl compounds, and explains how the steric and stereoelectronic effects control the same. The work comments on allylic strainsand their stereochemical control on different reactions with the related conformational control. It is a must read to understand the control elements, the prominent among these elements are spiro-conjuga
出版日期Book 20161st edition
關(guān)鍵詞Steric Effects; Stereoelectronic Effects; Orbital Symmetry and Orbital Overlap Effects; Stereoelectroni
版次1
doihttps://doi.org/10.1007/978-981-10-1139-9
isbn_softcover978-981-10-9339-5
isbn_ebook978-981-10-1139-9
copyrightSpringer Science+Business Media Singapore 2016
The information of publication is updating

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Diastereoselectivity in Organic Reactions,l, Anh–Felkin modification of Cram’s model, Houk’s transition structure model, Houk’s electrostatic model, Cieplak’s σ?→?σ*# model, and cation coordination model. The intricacies, variations, and predicted selectivities of these models are elaborated with examples. It has been argued that the Ciepla
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A(1,2) and A(1,3) Strains, facial selectivity of reactions such as [2,3] and [3,3] sigmatropic shifts, intramolecular S.2 reactions, hydroboration, enolate alkylation, etc. is highlighted. The high diastereoselectivity observed in the reactions of enolates derived from 4-substituted .-alkanoyl-1,3-oxazolidinones (Evans enola
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,The Conservation of Orbital Symmetry (Woodward–Hoffmann Rules), the symmetry characteristics of the σ, ., π and . molecular orbitals (MOs). This is followed by a description of the MOs and their symmetry characteristics for allyl cation, allyl radical, allyl anion, and 1,3-butadiene. This concept is applied to π.?+?π., π.?+?π. (Diels–Alder) and electrocyclic re
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,The Overlap Component of the Stereoelectronic Factor Vis-à-Vis the Conservation of Orbital Symmetryurse of pericyclic reactions as exemplified in this chapter. The orbital overlap factor has been discussed with a variety of examples such as the thermal fragmentations of cyclopropanated and cyclobutanated .-3,6-dimethyl-3,6-dihydropyridazine, and [1,5] sigmatropic shifts in .-2-alkenyl-1-alkylcycl
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Steric and Stereoelectronic Control of Organic Molecular Structures and Organic Reactions,plication of anomeric effect in 1,4-elimination reactions, including the preservation of the geometry of the newly created double bond, is elaborated. Finally, a brief discussion on the conformational profile of thioacetals and azaacetals is presented.
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