Titlebook: Single Molecule Toroics; Synthetic Strategies Keith Murray Book 2022 The Editor(s) (if applicable) and The Author(s), under exclusive licen

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Quantum Toroidicity in Single-Molecule Toroics: A Unifying Model Based on Heisenberg Spin Rings, achieve a degenerate ground state supporting a non-zero toroidal moment, the hallmark of Single-Molecule Toroics (SMTs). Our analysis goes beyond the semi-classical, non-collinear Ising model typically used to describe lanthanide-based SMTs, thus accounting for quantum tunnelling of toroidal states

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Introduction to Single-Molecule Toroics,r the removal of a magnetic field. Early dilution studies of this effect, however, readily demonstrated that . is resultant from the intrinsic magnetic anisotropy of the individual molecules and that, in fact, intermolecular interactions between constituent molecules are not necessary to observe the

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Mixed , Block Single-Molecule Toroics,escribed in detail, with MOLCAS methods employed to determine anisotropy directions, blocking barriers and relaxation effects and a newly developed model used to calculate magnetically coupled toroidal states and the role of these states in spin dynamics. The direct simulation of the micro-Squid mag

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