Titlebook: Ruthenium in Catalysis; Pierre H. Dixneuf,Christian Bruneau Book 2014 Springer International Publishing Switzerland 2014 Amide Bond Format

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Catalytic Transformations of Alkynes via Ruthenium Vinylidene and Allenylidene Intermediates,idene species have interesting chemical properties that make their reactivity different to that of the free and metal π-coordinated alkynes: the carbon α to the metal is electrophilic whereas the β carbon is nucleophilic. Ruthenium is one of the most commonly used transition metals to stabilize viny

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Visible-Light-Induced Redox Reactions by Ruthenium Photoredox Catalyst,e they can effectively catalyze single-electron-transfer (SET) processes by irradiation with visible light. These favorable properties of the catalysts provide a new strategy for efficient and selective radical reactions. Salts of tris(2,2′-bipyridine)ruthenium(II), [Ru(bpy).]., were first reported

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,C–C Bond Formation on Activation of Alkynes and Alkenes with (C5R5)Ru Catalysts,d molecules such as alcohols or water, often with atom economy. Various selective transformations are developed and can provide access to high multifunctional molecules. These reactions often proceed via an initial oxidative coupling leading to a ruthenacycle intermediate.

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1436-6002 pecific topic in organometallic chemistry.Research in this rThe series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the de

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Hydrogenation of Polar Bonds Catalysed by Ruthenium-Pincer Complexes,atures, mild hydrogen pressures, and can operate in absence of solvent with no generation of waste. The postulated mechanisms involve metal–ligand cooperation (MLC) by aromatization–dearomatization of the heteroaromatic pincer core.

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