Titlebook: Ruthenium Catalysts and Fine Chemistry; Christian Bruneau,Pierre H. Dixneuf Book 2004 Springer-Verlag Berlin Heidelberg 2004 Inorganic Che

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Ruthenium-Promoted Radical Processes Toward Fine Chemistry,methylcyclopentadienyl, or an indenyl ligand, and (3) ruthenium complexes bearing anionic carborane-phosphine and dicarbollide ligands. Their activities are discussed and the predictive value of cyclic voltammetry in radical chemistry is questioned. A related example of a ruthenium-catalyzed C–H hydroxylation reaction is also reported.

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Cyclopropanation with Ruthenium Catalysts,d diazoester derivatives producing cyclopropanecarboxylates with high stereoselectivity (.>. or .>trans) and enantioselectivity (over 90% ee). In order to attain their high performance, chiral or achiral nitrogen-based compounds have been synthesized and applied as ligands to control the activity of

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Ruthenium Vinylidenes and Allenylidenes in Catalysis, in organic synthesis [T. Naota, H. Takaya, S.I. Murahashi (1998) . 98:2599; B.M. Trost, F.D. Toste, A.B. Pinkerton (2001) . 101:2067; B.M. Trost BM (2002) . 35:695]. Ruthenium complexes bearing a carbenic ligand, such as a carbene, a vinylidene or an allenylidene group have found useful application