Titlebook: Rhodium Catalysis; Carmen Claver Book 2018 Springer International Publishing AG 2018 Decarbonylation reaction.Hydroformylation.Rhodium cat

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Book 2018chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbrev iated as Top Organomet Chem and cited as a journal..

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Tandem Rhodium Carbonylation Reactions,try, starting from abundant and low price substrates and avoiding the formation of substantial amounts of by-products. This atom-efficient tandem reaction approach shows that rhodium has a privileged place in the CO chemistry, not only to perform the hydroformylation reaction but also to functionalize the aldehyde function in a one-pot process.

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Rhodium Catalyzed Decarbonylation,fects as well as computational studies of model systems, which give an indication of the scope of the process. In this chapter, fundamental applications of Rh-catalyzed decarbonylation reactions are surveyed and discussed, including cross-coupling reactions, tandem reactions, and alternative methodologies for process intensification.

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,Rhodium-Catalyzed C–B Bond Formation,pleting the fifth section with a description and comments about the new trends on Rh-catalyzed C–H and C–X borylation. At the end of this chapter, the authors compile a summary and their perspective for the related field from a mechanistic point of view.

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,Rhodium Catalysts for C–S Bond Formation,s. Here, we summarize recent efforts in the reactions of cross coupling, C–H activation, metathesis, thiolation, carbothiolation, and hydrothiolation for the C–S bond formation catalyzed by rhodium complexes, particularly highlighting the synthetic and mechanistic aspects.