Titlebook: Redox Systems Under Nano-Space Control; Toshikazu Hirao Book 2006 Springer-Verlag Berlin Heidelberg 2006 Coordination Chemistry.catalysis.

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Through-Space Control of Redox Reactions Using Interlocked Structure of Rotaxanessumed that the redox reaction of the ferrocene moiety accompanied the transposition of the wheel component on the axle. The reduction of ketoneby the action of rotaxane bearing the dihydronicotinamide groupwas also investigated. The activity of the dihydronicotinamide groupwas considerably enhanced

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Electronic Properties of Helical Peptide Derivatives at a Single Molecular Leveldistance through helical peptides is explained by the electron hopping between amide bonds. When naphthyl groups were linearly arranged along the helix scaffold, the electron hopping between naphthyl groups via anion radical was also observed. The aromatic linker between gold and the peptide acceler

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Construction of Redox-Induced Systems Using Antigen-Combining Sites of Antibodies and Functionalizatyrins was found to control photoinduced electron transfer from porphyrin to electron acceptor molecules. One of the antibodies against a cationic porphyrin bound Fe-porphyrin strongly, and the complex of Fe-porphyrin with the antibody showed peroxidase activity. We expanded our study to include the

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Realizing the Ultimate Amplification in Conducting Polymer Sensors: Isolated Nanoscopic Pathwaysired restrictions in carrier transport and present analysis that supports the assertion that chemoresitive materials with isolated pathways offer great potential for the creation of ultrasensitive sensors.

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Redox Active Architectures and Carbon-Rich Ruthenium Complexes as Models for Molecular Wiresn-rich chains and to mediate electron transfer processes between functionalities at the end of these chains. These models constitute new keys to reach functionalized materials composed of transition metals and carbon-rich chains and bridges in conjugated oligomers or star molecules.

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