Titlebook: Radicals in Synthesis I; Methods and Mechanis Andreas Gans?uer Book 2006 Springer-Verlag Berlin Heidelberg 2006 Stereochemistry.experiment.

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Vincent Darmency,Philippe Renaudds of research. The articles in this volume highlight a range of these applications and provide introductory material for topics covered in the IMA workshops on "Optimization and Control" and "Applications in Biology, Dynamics, and Statistics" held during the IMA year on Applications of Algebraic Ge

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Jake Zimmerman,Mukund P. Sibity of fields of research. The articles in this volume highlight a range of these applications and provide introductory material for topics covered in the IMA workshops on "Optimization and Control" and "Applications in Biology, Dynamics, and Statistics" held during the IMA year on Applications of Al

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H. Zipseds of research. The articles in this volume highlight a range of these applications and provide introductory material for topics covered in the IMA workshops on "Optimization and Control" and "Applications in Biology, Dynamics, and Statistics" held during the IMA year on Applications of Algebraic Ge

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Free-Radical

,Generation of Alkene Radical Cations by Heterolysis of β-Substituted Radicals: Mechanism, Stereochelizations, nucleophilic attack, and tandem nucleophilic attack/radical cyclization processes. Stereochemical memory effects arising from the order within the contact alkene radical cation/anion pair are discussed at the level of both diastereoselectivity and enantioselectivity.

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Tin-Free Radical Reactions Mediated by Organoboron Compounds,agents in radical process. This review summarizes the results obtained with organoboron compounds as a?source of alkyl radicals. Four different strategies are described, i.e., the use of organoboranes as radical initiators, as a?source of alkyl radicals, as chain transfer reagents, and finally as reducing agents.

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,Generation of Alkene Radical Cations by Heterolysis of β-Substituted Radicals: Mechanism, Stereocheviewed, and a?general mechanism involving contact alkene radical cation/anion pairs is presented for both fragmentation reactions and rearrangements. The available kinetic data for both fragmentations and migrations are summarized. The β-(acyloxy)alkyl and β-(phosphatoxy)alkyl radical rearrangements

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