Titlebook: Radical Ionic Systems; Properties in Conden A. Lund,M. Shiotani Book 1991 Springer Science+Business Media Dordrecht 1991 chemistry.crystal.

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Deuterium Labelling Studies of Cation Radicalsand difficulties with their generation have been obstacles to the study of representative organic and inorganic cation radicals This changed with the development of halocarbon and noble gas matrix isolation techniques combined with ionizing radiations as applied to ESR spectroscopy by Shida [.] and

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Study of Radical Cations by Time-Resolved Magnetic Resonancerly chemical events induced by ionizing or photoionizing radiation. The development of specialized time-resolved magnetic resonance tools has allowed us to dispense with a key element that has been vital to a wide range of radical cation studies using static EPR, i.e., a stabilizing (rigid, chemical

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Radical Cations in Pulse Radiolysis are usually very reactive. In condensed matter radical cations interact with their neighboring molecules forming solvation shells. This is also important for cations in non-polar liquids. Solvation of the cations occurs probably within picoseconds. For liquids such as alkanes or carbon tetrachlorid

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Trapped Anions in Organic Crystalspy. The study makes it possible to precisely determine ESR parameters such as g, hyperfine, and quadrupole tensors. The geometrical and electronic structures of the radicals can be deduced from these parameters by comparing the tensor axes with the molecular orientation in the crystals. Analysis of

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Anion Radicals in Inorganic Crystalss with polyatomic ions yielded well-resolved ESR signals after exposure to ionizing radiation. The ESR signals were initially assigned to paramagnetic ‘centers’ in analogy with the results of previous studies of radiation damage in alkali halides. It eventually became apparent, however, that the obs

Friction

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