Titlebook: Part I: Physical Chemistry. Part II: Solid State Physics; Arthur S. Wightman Book 1997 Springer-Verlag Berlin Heidelberg 1997 Electronic S

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Calculation of the Rate of Elementary Association Reactionsr, the calculated values are somewhat too low, which cannot be explained by an inaccuracy of the method. Reasons for the discrepancy other than the possible nonadiabatic character of the reaction are discussed.

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erry phases. Although few in number, Wigner‘s articles on solid-state physics laid the ground for the modern theory of the electronic structure of metals. W. Kohn writes about this in his annotation to Part 2 of the book and he also points out Wigner‘s great influence in the development of solid-state theory.978-3-642-63824-4978-3-642-59033-7

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physics. In his annotation to the first part, N. Balazs clearly points out Wigner‘s role in early quantum chemistry and applied statistical mechanics. One corner stone was his introducing of what is now called the Wigner function, and his paper on adiabatic perturbations foreshadowed later work on B

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Bildung und Zerfall von Molekülen Gegenproze?, n?mlich der spontane Zerfall eines Moleküls, vor sich gehen kann. Als Begründung wird angeführt, da? es unendlich unwahrscheinlich ist, da? die Relativenergie der zusammensto?enden Gebilde gerade einen quantenhaft zul?ssigen Energiewert des zu bildenden Moleküls betr?gt.