| 書目名稱 | Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis | | 編輯 | Michel Chanon,Michel Julliard,Jean Claude Poite | | 視頻video | http://file.papertrans.cn/742/741127/741127.mp4 | | 叢書名稱 | Nato Science Series C: | | 圖書封面 |  | | 描述 | When one considers the overall representation of frontier orbital filling of hexacoordinate (Oh) and tetracoordinate (Td) inorganic and organo- metallic complexes, it clearly appears that out of 26 cases covering both high spin and low spin situations, 21 represent paramagnetic species (K. Purcell, J. Kotz, "Inorganic Chemistry", Saunders, 1977, p561). This would suggest that, if there is a part in chemistry to illustrate the reactivity of radical species, this part certainly is inorganic organometallic chemistry. In contrast with these expectations, and whereas the standard Organic Chemistry textbook (J. March ,"Advanced Organic Chemistry", J. Wiley, N. Y. , 1985) has a specific chapter devoted to free radical reactivity, neither the inorganic standard (FA Cotton, G. Wilkinson, "Advanced Inorganic Chemistry", Wiley, 1988), nor the Organometallic one (J. P. Collman, L. S. Hegedus, J. R. Norton, R. G. Finke, "Principles and Applications of Organotransition Metal Chemistry", University Science Books Mill Valley C. A. , 1987) possess such a specific chapter. The balance is partly restored because the two last cited books have a more comprehensive treatment of electron transfer phenome | | 出版日期 | Book 1989 | | 關(guān)鍵詞 | Coupling reaction; Nucleophilic substitution; catalysis; organic chemistry; organic synthesis; synthesis | | 版次 | 1 | | doi | https://doi.org/10.1007/978-94-009-0877-2 | | isbn_softcover | 978-94-010-6882-6 | | isbn_ebook | 978-94-009-0877-2Series ISSN 1389-2185 | | issn_series | 1389-2185 | | copyright | Kluwer Academic publishers 1989 |
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