Titlebook: Organotransition-Metal Chemistry; Yoshio Ishii,Minoru Tsutsui Book 1975 Plenum Press, New York 1975 chromium.inorganic chemistry.iron.meta

美學(xué)

Mawkish

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FOIL

syring

Polycyanovinyl Transition Metal Derivativesl halides, which are relatively unreactive towards nucleophiles. Such considerations suggested reactions of polycyanovinyl halides with metal carbonyl anions. as a method for the preparation of novel polycyanovinyl transition metal derivatives.

無(wú)節(jié)奏

oxidant

考博

記憶

Novel Rhodium and Palladium Complexes with Benzoyl and Thiobenzoyl Isocyanates as Ligands). or with RhCl(CO)(Ph.P).. A cationic complex [(bipy)Rh(Ph.P).(PhCS·NCO)].BPh. (6a) was also obtained. The similar reactions of Pd.(DBA). with 4 and bipyridine or o-phenanthroline afforded (N-N)Pd-(PhCS·NCO) complexes (7). Most of these novel complexes have a metallocyclic structure composed of M-O-C-N-C or M-S-C-N-C skeletons.

氣候

A New Preparation of Organocopper(I)-Isonitrile Complexes and Their Reactionsf Cu(O) isonitrile complex. Moreover, esr spectra. of the mixture of metallic copper or Cu.O and π-substrates such as .- and .-dinitrobenzene, nitrobenzene, benzoquinone, fluorene and tetracyanoethylene in isonitrile exhibited the resolved signals of the corresponding organic radical anions.

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