Titlebook: Organic Syntheses by Oxidation with Metal Compounds; W. J. Mijs,C. R. H. I. Jonge Book 1986 Plenum Press, New York 1986 Aromaticity.Rearra

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Oxidations of Organic Compounds with Osmium Tetroxide,kaline medium. Apart from synthetic applications in the laboratory these oxidants are also important in industrial syntheses. Osmium tetroxide is the oldest compound and has been generally used for hydroxylation of olefins. Ruthenium tetroxide reacts in the same way as a vigorous oxidant even under

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Thallium(III) Salts as Oxidants in Organic Synthesis,s, however, which are very readily oxidized to the trivalent state and the chemistry of which is not at all well developed, thallium(I) salts are stable. Indeed, it has been accurately stated that “… for thallium the Tl.–Tl. relationship is a dominant feature of the chemistry.”. This is certainly tr

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Bismuth-Salt Oxidations,bismuth were found to display oxidizing power. Bismuth(V) in the form of sodium bismuthate is an oxidant analogous to lead tetraacetate, being fairly specific for the fission of 1,2-diols. During the study of sodium bismuthate it was discovered that bismuth(III) salts can oxidize α-hydroxyketones to

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