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Titlebook: Optical Studies in Liquids and Solids; Academician D. V. Skobel’tsyn (Director) Book 1969 Springer Science+Business Media New York 1969 Vi

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31#
發(fā)表于 2025-3-26 23:54:12 | 只看該作者
ecular structure. These vibrations ap- pear directly in the infrared absorption spectra and Raman spectra of gases, liquids, and solids. A measurement of the number of bands in addition to their positions (frequencies or wavelengths) offers the possibility of obtaining a great deal of important info
32#
發(fā)表于 2025-3-27 02:09:56 | 只看該作者
33#
發(fā)表于 2025-3-27 06:30:00 | 只看該作者
34#
發(fā)表于 2025-3-27 13:07:31 | 只看該作者
Theory of the Spectral Composition of the Depolarized Scattering of Light in Liquids isotropic state; we define this tensor so that its mean value over the volume is zero (medium isotropic on average). The tensor S. should be a function of the angles determining the orientation of the axes of the molecules relative to the stationary (laboratory) system of coordinates x, y, z (indices i, k, etc.).
35#
發(fā)表于 2025-3-27 15:16:58 | 只看該作者
Experimental Resultss. In addition to this, the cyclohexane molecule has a high symmetry; vibrational calculations have already been carried out for it [27–29], so that it is much easier to interpret the second-order lines in the vibrational spectra of this molecule. The second-order lines in the Raman spectrum of cyclohexane were accordingly studied in [6].
36#
發(fā)表于 2025-3-27 20:09:38 | 只看該作者
37#
發(fā)表于 2025-3-28 00:26:24 | 只看該作者
Appearance of the Rotional Oscillations of Methyl Groups in Low-Frequency Raman Spectraf the CH. group, only deformation oscillations can appear in the spectrum. We can hardly expect substantial intermolecular interactions in these substances. The latter factor facilitates analysis of the results obtained.
38#
發(fā)表于 2025-3-28 03:55:22 | 只看該作者
39#
發(fā)表于 2025-3-28 08:09:01 | 只看該作者
Review of Literature and Presentation of the Problemdely differing problems and are often of a random nature. Data relating to the second-order infrared spectral lines of molecules which we have studied will be included in the appropriate sections of this treatment.
40#
發(fā)表于 2025-3-28 10:49:53 | 只看該作者
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