Titlebook: Optical Spectra and Chemical Bonding in Transition Metal Complexes; Special Volume II, d T. Sch?nherr Book 2004 Springer-Verlag Berlin Heid

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Allowed and Forbidden d-d Bands in Octahedral Coordination Compounds: Intensity Borrowing and Internd interference dips. These effects are quantitatively analyzed with modern theoretical models based on coupled potential energy surfaces. Both effects can be rationalized in terms of quantum interference processes.

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Photoluminescence and Excitation Energy Transfer of Rare Earth Ions in Nanoporous Xerogel and Sol-Gokuchi-Hirayama model of single step energy transfer. The critical distance of energy transfer .. is found to be 0.9 nm (±10%) on the average, irrespective of models, temperatures and matrices. The experimental results give evidence of the fact that the trapping-limited energy transfer mechanism is dominant in the disordered nanomatrices.

雄偉

Progress in Hole-Burning Spectroscopy of Coordination Compounds,to a wide range of problems in chemistry, physics and biology. The present chapter reviews recent progress made by hole-burning experiments in the spectroscopy of coordination compounds, in particular chromium(III) complexes.

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0081-5993 g.Short and concise reports, each written by the world‘s renAxel Christian Klixbüll J?rgensen was a “Polyhistor”,one of the very few in the highly specialized science of our time.His interests and contributions in ch- istry covered the whole Periodic Table.This statement demonstrates the breadth of

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Recent Advances of Spin Crossover Research,y irradiation and magnetic field, will be discussed. Progress in theoretical treatments of spin crossover phenomena, particularly cooperativity, will be briefly outlined. The chapter concludes with a summary of research highlights published by the partner laboratories of the TMR network TOSS.

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,The Angular Overlap Model and Vibronic Coupling in Treating s-p and d-s Mixing – a DFT Study,the DFT analysis of spectral data for some model complexes. The equivalence of the vibronic coupling approach on the MO level with the AOM is emphasized; the advantage of the AOM is, however, that angular and radial (bond length) contributions can be cleanly separated.

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