Titlebook: On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes; Terrance John Hadlington Book 2017 Springer International Publishing

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The Development of Extremely Bulky Amide Ligands and Their Application to the Synthesis of Group 14successful applied in such MG chemistry: chelating ligands and mono-dentate ligands. Here, some of the more important examples of such ligands will be discussed, as will their use in the synthesis of group 14 element halide complexes, alongside our efforts in this regard.

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Stoichiometric Reactivity and Catalytic Applications of Heavier Tetrylene Derivatives, context of catalysis has seen much attention. Advances in the area of small-molecule activation by group 14 element(II) complexes will be discussed herein, followed by our efforts in this regard toward ?their applications in efficient, well defined catalytic regimes.

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Reactivity of Low-Coordinate Group 14 Element(II) Hydride Complexes,or. This chemistry will be dicussed in this chapter, leading to our research which has taken this a step further, involving facile E-H bond addtion to unactivated unsaturates such as alkenes, in some cases reversibly. Such reactivity is implicit in countless known catalytic cycles.

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