Titlebook: Non-Covalent Multi-Porphyrin Assemblies; Synthesis and Proper Enzo Alessio Book 2006 Springer-Verlag Berlin Heidelberg 2006 Rhenium.bonding

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Thermodynamics of Metal-Mediated Assemblies of Porphyrins,ed. The topic is discussed in order of increasing complexity, from simple acyclic assemblies to multicyclic assemblies, by emphasizing the role played by two fundamental physicochemical quantities, namely, the stability constant of the metalloporphyrin-ligand interaction and the effective molarity,

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Porphyrin Rotaxanes and Catenanes: Copper(I)-Templated Synthesis and Photoinduced Processes,porphyrins and gold(III) porphyrins were chosen as electron donors and electron acceptors, respectively, to constitute the electro- and photoactive parts of the present systems. The processes—energy and electron transfer reactions—occurring in the interlocked structures upon light absorption in the

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自傳

Metal-Mediated Multi-Porphyrin Discrete Assembliesand Their Photoinduced Properties, inrecent years. In this review, we summarize recent work in this field from our and other laboratories.The photophysical properties of some ruthenium-mediated assemblies of porphyrins prepared by our groupare also described.

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Rhenium-Linked Multiporphyrin Assemblies:Synthesis and Properties,e been used for chemical sensing, oxidative catalysis, and light-to-electrical energy conversion. The assemblies have also been used to investigate fundamental aspects of light-induced energy and electron transfer.

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Thermodynamics of Metal-Mediated Assemblies of Porphyrins,the latter being a?measure of the ease of formation of a?given cyclic structure or substructure. Criteria to assess cooperativity in self-assembly are also discussed. The principles are illustrated by selected examples involving metal-mediated assemblies of porphyrins in which the metal is incorporated into the porphyrin ring.

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Porphyrin Rotaxanes and Catenanes: Copper(I)-Templated Synthesis and Photoinduced Processes,presence or absence of Cu(I) are presented, their rates and efficiencies critically compared and discussed with respect to properties of the components and of the ensemble. A?detailed examination of differences and analogies in photoreactivity between the present and closely related systems reported by others is presented.

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Enzo AlessioPresents critical reviews of the present position and future trends in modern chemical research concerned with chemical structure and bonding.Short and concise reports, each written by the world‘s ren

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