Titlebook: New Methodologies and Techniques for a Sustainable Organic Chemistry; Alessandro Mordini,Ferenc Faigl Conference proceedings 20081st editi

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Catalytic Asymmetric Synthesis With Novel Monodentate Phosphorus Ligands,ntate phosphorus ligands have exhibited excellent enantioselectivity in the Pd-catalyzed asymmetric allylic alkylation, Rh-catalyzed asymmetric hydrogenation and hydroformylation, and Cu-catalyzed conjugate addition reactions.

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New Cyclization and Cycloaddition Reactions in Organic Synthesis,d cascade carbocyclizations, including carbonylative carbocyclizations, provide powerful methods for the rapid construction of heterocyclic as well as carbocyclic compounds in one step. Efficient [2 + 2 + 2 + 1] cycloaddition process also furnishes an easy access to fused tricyclic systems. Cyclohyd

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,New Chiral Catalysts for C–C-bond Formations,r as the sole stereogenic element has been introduced, and use of such, sulfoximines’ leads to products with excellent enantioselectivities in asymmetric C–C-bond forming reactions and imine hydrogenations. For large-scale applications, the synthetic access of sulfoximines had to be improved. In add

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Homogeneous and Heterogeneous Catalysis Using Base Metals From Groups 10 And 11, The new reagent for synthesis, nickel-on-graphite (Ni/C.) is presented as a means of catalyzing the reductions of aryl tosylates and mesylates. Another reagent under development, copper-in-charcoal (Cu/C) is described and its potential to effect heterogeneous asymmetric hydrosilylations in the pres