Titlebook: New Methodologies and Techniques for a Sustainable Organic Chemistry; Alessandro Mordini,Ferenc Faigl Conference proceedings 20081st editi

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978-1-4020-6792-1Springer Science+Business Media B.V. 2008

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New Methodologies and Techniques for a Sustainable Organic Chemistry978-1-4020-6793-8Series ISSN 1568-2609

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Alessandro Mordini,Ferenc FaiglNew concepts and results for sustainable organic chemistry.Discusses the problems of environmentally benign organic processes on an interdisciplinary approach.World-renowned experts in the fields of s

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Catalytic Asymmetric Synthesis With Novel Monodentate Phosphorus Ligands,ntate phosphorus ligands have exhibited excellent enantioselectivity in the Pd-catalyzed asymmetric allylic alkylation, Rh-catalyzed asymmetric hydrogenation and hydroformylation, and Cu-catalyzed conjugate addition reactions.

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Intramolecular Reactions of Alkynes with Alkenes Catalyzed by Platinum and Gold,yne and the alkene, an oxidative cyclometallation can ensue to give a metallacyclopentene, which usually evolves by β-hydrogen elimination (Alder-ene cycloisomerization). Alternatively, the selective coordination of the metal to the alkyne promotes an attack of the alkene (usually .) to give cyclopropyl metal carbenes.

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Homogeneous and Heterogeneous Catalysis Using Base Metals From Groups 10 And 11, The new reagent for synthesis, nickel-on-graphite (Ni/C.) is presented as a means of catalyzing the reductions of aryl tosylates and mesylates. Another reagent under development, copper-in-charcoal (Cu/C) is described and its potential to effect heterogeneous asymmetric hydrosilylations in the presence of an inexpensive silane is disclosed.

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,Adventures In Microwave-assisted Organic Synthesis: Contributions From The Kappe Laboratory 2000–20ria. The focus of the article is on synthetic applications in the area of heterocyclic chemistry, multicomponent reactions, transition metalcatalyzed processes, solid-phase synthesis and combinatorial chemistry.

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