Titlebook: Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations; Bernard Meunier Book 2000 Springer-Verlag Berlin Heidelberg 2000 Biochemie.Bio

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Jean-Jacques Girerd,Frédéric Banse,Ariane Jalila Simaan

SPASM

Waldemar Adam,Catherine M. Mitchell,Chantu R. Saha-M?ller,Oliver Weichold

Atheroma

Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations

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裁決

未成熟

SPECT

0081-5993 . The description of these metal-oxo and metal-peroxo species is based on physico-chemical data, reactivity results and also on theoretical calculations.978-3-662-15663-6978-3-540-46592-8Series ISSN 0081-5993 Series E-ISSN 1616-8550

HATCH

Active Iron-Oxo and Iron-Peroxo Species in Cytochromes P450 and Peroxidases; Oxo-Hydroxo Tautomerisoxylation, epoxidation, .- or .-oxide formation, etc.) which are mediated by an electrophilic oxidative species. The second class is represented by the oxidative deformylation of aldhehydes and involves a nucleophilic oxidant as active intermediate. The reductive activation of molecular oxygen by cy

paragon

Nucleophilicity of Iron-Peroxo Porphyrin Complexes,s. This review focuses on one of those postulated intermediates, the ferric heme peroxo complex, [(porphyrin)Fe(III)(O. .)]., a species which has been postulated to be formed transiently in the P450 catalytic cycle. Ferric peroxo porphyrin complexes, inorganic complexes that model the peroxo species

antedate

Characterization of High-Valent Oxo-Metalloporphyrins,s mediated by synthetic metalloporphyrins. In this review, we survey studies of high-valent oxo metalloporphyrins in the past decade. In Sect. 2, electronic structures and magnetic properties of compound I and compound II species in various heme enzymes are discussed on the basis of recent studies o