Titlebook: Mechanistic Models of Asymmetric Reductions; Atsuyoshi Ohno,Satoshi Ushida Book 1986 Springer-Verlag Berlin Heidelberg 1986 Coenzym.amino

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Book 1986e of the undertaking will become clear and that it will find resonance among the scientific community interested in the thoughtful application of chemical and physical con- cepts to biochemical and molecular-biological problems.

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the profile of the undertaking will become clear and that it will find resonance among the scientific community interested in the thoughtful application of chemical and physical con- cepts to biochemical and molecular-biological problems.978-3-540-16440-1978-3-642-48868-9

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https://doi.org/10.1007/978-3-642-48868-9Coenzym; amino acid; biochemistry; biology; chemistry; chirality; enzyme; enzymes; organic chemistry; synthes

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Asymmetric Reduction by Model Compounds of NAD(P)H,rogen is substituted by a simple substituent, such as 1-propyl-1,4-dihydronicotinamide (PNAH), 1-benzyl-1,4-dihydronicotinamide (BNAH), or Hantzsch ester (HEH), can be considered as a model compound for NAD(P)H.

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Diastereo-Differentiation at the 4 Position of 1,4-Dihydropyridine,It is concluded, as described in the previous section, that the most important factor for the stereoselectivity of reduction is the selection of the transferring hydrogen from the prochiral position.

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,Asymmetric Synthesis of α-Amino Acids,It has been emphasized that the most important factor determining the efficiency of asymmetric induction by a chiral NAD(P)H-model compound is the effectiveness in discriminating between the . and si-faces of the dihydropyridine ring. A similar effect also operates in the stereochemistry of transamination mediated by pyridoxamine, vitamin B..

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978-3-540-16440-1Springer-Verlag Berlin Heidelberg 1986

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