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Titlebook: Late Transition Metal-Carboryne Complexes; Synthesis, Structure Zaozao Qiu Book 2012 The Editor(s) (if applicable) and The Author(s), under

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書目名稱Late Transition Metal-Carboryne Complexes
副標(biāo)題Synthesis, Structure
編輯Zaozao Qiu
視頻videohttp://file.papertrans.cn/582/581784/581784.mp4
概述Nominated by The Chinese University of Hong Kong as an outstanding PhD thesis.Ground-breaking new work in metal-carboryne chemistry.Inspiration for future work on synthetic, cluster and materials chem
叢書名稱Springer Theses
圖書封面Titlebook: Late Transition Metal-Carboryne Complexes; Synthesis, Structure Zaozao Qiu Book 2012 The Editor(s) (if applicable) and The Author(s), under
描述Zaozao Qiu shows in this thesis that transition metals can mediate or catalyze the cycloaddition or coupling reactions of carboryne with alkynes or alkenes to afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes. These results represent powerful strategies to assemble useful complex molecules from very simple precursors in a single operation. Carboranes have many applications in medicine. However, their unique structures make derivatization difficult and the limited efficient synthetic methods to obtain functional carborane materials have restricted applications of carboranes within a narrow scope. This work breaks a new ground in metal-carboryne chemistry and will have a significant impact on synthetic, cluster and materials chemistry.
出版日期Book 2012
關(guān)鍵詞carborane; carboryne; coupling reaction; cycloaddition reaction; metal-carboryne; prize thesis
版次1
doihttps://doi.org/10.1007/978-3-642-24361-5
isbn_softcover978-3-642-43502-7
isbn_ebook978-3-642-24361-5Series ISSN 2190-5053 Series E-ISSN 2190-5061
issn_series 2190-5053
copyrightThe Editor(s) (if applicable) and The Author(s), under exclusive license to Springer-Verlag GmbH, DE
The information of publication is updating

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Late Transition Metal-Carboryne Complexes978-3-642-24361-5Series ISSN 2190-5053 Series E-ISSN 2190-5061
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Nickel-Mediated Coupling Reaction of 1,2-,-Carboryne with Alkenes,Metal-benzyne complexes have found many applications in organic synthesis, mechanistic studies, and the synthesis of functional materials. In contrast, their analogues, metal-1,2-.-carboryne complexes are largely unexplored although the reactivity pattern of 1,2-.-carboryne (generated in situ) has been actively investigated.
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Introduction,try, remarkable thermal and chemical stability, and a hydrophobic molecular surface. Medical applications of the carboranes have been mainly in the field of boron neutron capture therapy (BNCT) of cancer, utilizing the high boron content of the carboranes.
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