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Antje Hecheltjen,Frank Thonfeld,Gunter Menzgative .-centers. Shallow/deep center instability. Metastable Lattice relaxation. Transition metal impurities, energy tabulation. Isoelectronic defects, charge character. Tabulation of deep center energies and effective crystal field splitting. Measured ionization energies in Ge, Si, GaAs, and CdS.