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Titlebook: Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation; Arimasa Matsumoto Book 2014 Springer Japan 2014 Alkyne Annul

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發(fā)表于 2025-3-21 17:36:38 | 只看該作者 |倒序?yàn)g覽 |閱讀模式
書(shū)目名稱(chēng)Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation
編輯Arimasa Matsumoto
視頻videohttp://file.papertrans.cn/476/475418/475418.mp4
概述Nominated by The University of Tokyo as an outstanding Ph.D. thesis.Provides examples of C-H bond activation which has attracted attention as an important chemical reaction in organic chemistry.Shows
叢書(shū)名稱(chēng)Springer Theses
圖書(shū)封面Titlebook: Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation;  Arimasa Matsumoto Book 2014 Springer Japan 2014 Alkyne Annul
描述Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium. This thesis describes the first practical example of iron catalysis in the carbon–hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C–H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.
出版日期Book 2014
關(guān)鍵詞Alkyne Annulation; C–H Bond Activation; Fused Aromatic Compounds; Iron Catalysis; Iron Catalyst; Naphthal
版次1
doihttps://doi.org/10.1007/978-4-431-54928-4
isbn_softcover978-4-431-56248-1
isbn_ebook978-4-431-54928-4Series ISSN 2190-5053 Series E-ISSN 2190-5061
issn_series 2190-5053
copyrightSpringer Japan 2014
The information of publication is updating

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Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Grignard Reagent,idant to give 9,10-disubstituted or 9-substituted phenanthrenes and congeners. The reaction proceeded under mild conditions and bromide, chloride, trimethylsilyl, trifluoromethyl, and olefinic groups were tolerated. Mechanistic investigations suggest that this reaction involves a 5-membered ferracycle formation via C–H bond activation.
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2190-5053 s an important chemical reaction in organic chemistry.Shows Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as p
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Book 2014ue combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C–H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.
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Arimasa Matsumotoal students at the University of Washington. These materials included handouts, practice problems, guides to reading research articles, quizzes, notes from student help sessions, and student emails. The primary goal of these written materials, and now this book, is to recreate the perspective of lea
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