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Titlebook: Iron-Catalyzed C-H/C-H Coupling for Synthesis of Functional Small Molecules and Polymers; Takahiro Doba Book 2023 The Editor(s) (if applic

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發(fā)表于 2025-3-21 19:02:48 | 只看該作者 |倒序?yàn)g覽 |閱讀模式
書目名稱Iron-Catalyzed C-H/C-H Coupling for Synthesis of Functional Small Molecules and Polymers
編輯Takahiro Doba
視頻videohttp://file.papertrans.cn/476/475417/475417.mp4
概述Nominated as an outstanding Ph.D. thesis by the University of Tokyo.Presents iron as a catalyst for materials synthesis.Gives detailed mechanistic insights to help the reader understand iron catalysis
叢書名稱Springer Theses
圖書封面Titlebook: Iron-Catalyzed C-H/C-H Coupling for Synthesis of Functional Small Molecules and Polymers;  Takahiro Doba Book 2023 The Editor(s) (if applic
描述This thesis describes the development of iron-catalyzed thienyl C–H/C–H coupling. This is applied to the synthesis of highly conjugated and electron-rich thiophene compounds of interest in materials science by utilization of low redox potential of iron in combination with a mild oxalate oxidant..Transition-metal-catalyzed C(sp2)–H/C(sp2)–H coupling has attracted much attention as one of the most straightforward methods to construct C(sp2)–C(sp2) bonds. However, application of this ideal transformation to the synthesis of redox-sensitive pi-materials was hindered by the requirement of a strong oxidant for catalyst turnover. This limitation originates primarily from the large redox potential of conventional transition-metal catalysts such as palladium and rhodium.?.This thesis shows that the efficiency of C–H activation was significantly improved by introduction of a new conjugated tridentate phosphine ligand, giving direct access to polymeric thiophene materials from simple thiophene monomers. Considering the importance of environmentally friendly organic synthesis in terms of UN Sustainable Development Goals, the reactions described herein highlight the potential of iron, the most
出版日期Book 2023
關(guān)鍵詞Iron Catalysis; C–H Activation; C–H/C–H Coupling; Thiophene Materials; Organic Electronics
版次1
doihttps://doi.org/10.1007/978-981-99-4121-6
isbn_softcover978-981-99-4123-0
isbn_ebook978-981-99-4121-6Series ISSN 2190-5053 Series E-ISSN 2190-5061
issn_series 2190-5053
copyrightThe Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapor
The information of publication is updating

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2190-5053 iophene monomers. Considering the importance of environmentally friendly organic synthesis in terms of UN Sustainable Development Goals, the reactions described herein highlight the potential of iron, the most 978-981-99-4123-0978-981-99-4121-6Series ISSN 2190-5053 Series E-ISSN 2190-5061
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al research literature. More than ever, a clear understanding of the fundamental aspects of Epidemiology and Biostatistics is needed to successfully navigate the increasingly complex methods utilized by modern clinical research studies. This book could not have been created without the dedicated hel
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Takahiro Dobaal research literature. More than ever, a clear understanding of the fundamental aspects of Epidemiology and Biostatistics is needed to successfully navigate the increasingly complex methods utilized by modern clinical research studies. This book could not have been created without the dedicated hel
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Iron-Catalyzed C-H/C-H Coupling for Synthesis of Functional Small Molecules and Polymers
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