Titlebook: Iron Phosphate Materials as Cathodes for Lithium Batteries; The Use of Environme Pier Paolo Prosini Book 2011 Springer-Verlag London Limite

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Triphylite,of conductive LiFePO. particles with outstanding electrochemical properties. Electrochemical tests were made at 80°C using a polymer electrolyte. They claimed that the active material was able to deliver almost the full theoretical capacity when discharged at a current density as high as 170 A kg..

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Determination of the Diffusion Coefficient of LiFePO4,ffusion coefficient as a function of the composition unclear. In such a case, the chemical diffusion coefficient as obtained from GITT and IS measurements, may be taken as an effective measure which reflects the intensity of long- and short-range interactions between the intercalated species. The in

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Vivianite and Beraunite,tion of Fe.. It is well known that natural ferrous phosphate (vivianite) rapidly oxidizes on exposure to air, passing through deepening shades of blue to finally become brown beraunite (3Fe.O.?2P.O.?10H.O). The vivianite obtained by the sol–gel route was dried in air at 100°C. The so-obtained materi

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Amorphous Iron Phosphate,.6H.O and NH.H.PO., using hydrogen peroxide as an oxidizing agent. The material was characterized by chemical analysis, TG/DTA, XRD, and SEM. The material was tested as a cathode in non-aqueous lithium cells. Galvanostatic intermittent titration technique (GITT) was used to follow the lithium interc

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Nano-Crystalline LiFePO4,as a cathode for lithium-ion batteries (Prosini, J. Electrochem. Soc. .:A886–A890, 2002). Nano-crystalline LiFePO. showed very good electrochemical performance delivering the full theoretical capacity (170 Ah kg.) when cycled at 17 A kg. at room temperature. A capacity fade of about 0.25 % per cycle

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Long-Term Cyclability of Nano-Crystalline LiFePO4,sulting from volume variations during lithium extraction. The fading decreased upon cycling and after the 200. cycle the material was able to intercalate/deintercalate lithium for more than 500 cycles without further capacity decline.

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Versatile Synthesis of Carbon-Rich LiFePO4,ical performance. In this chapter we stress this concept reporting on a new reproducible synthetic route to prepare nano-particle LiFePO./C composites, in which the phosphorus, iron and carbon atoms all originate from the same precursor. LiFePO./C composites were prepared from thermal decomposition

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Modeling the Voltage Profile for LiFePO4, a Li-deficient shell while the Li-rich shell is formed on the Li-deficient core upon discharge. Delmas et al. (Nat. Mater. .:665–671, 2008) proposed a “domino-cascade model” in which the existence of structural constraints, occurring just at the reaction interface, lead to the minimization of the e

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ls as Cathodes for Lithium Batteries. is written for postgraduate students and researchers in electrochemistry, R&D professionals and experts in electrochemical storage..978-1-4471-6075-5978-0-85729-745-7