Titlebook: Ionic Polymerizations and Related Processes; Judit E. Puskas,Armin Michel,Shahzad Barghi Book 1999 Springer Science+Business Media Dordrec

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Newer Aspects of Photoinitiated Cationic Polymerization,zation of various mono and multifunctional vinyl and heterocyclic monomers. Such monomerphotoinitiator systems can be used in a wide variety of applications including protective and decorative coatings, printing inks and adhesives. Mechanisms for the photolysis of the photoinitiators and their actio

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Cationic Macromolecular Design Using Non(HOMO)Polymerizable Monomers,diate capping reaction of living polyisobutylene with non(homo)polymerizable monomers, such as 1,1-diphenylethylene derivatives or 2-alkylfurans. Kinetic and mechanistic aspects of this capping reaction is discussed, and an overview of capping and coupling reactions is presented as advanced tools fo

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Segmented Polymer Networks by Cationic Polymerization: Design and Applications,aking use of macromolecular design concepts of cationic polymerization. The acrylate end groups of the bis-macromonomers have been radically copolymerized with vinyl monomers such as methyl methacrylate, butyl acrylate and hydroxyethyl acrylate for the synthesis of hydrophobic, amphiphilic or hydrop

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Kinetics of the Living Polymerization of Isobutylene,io, solvents and initiator type. It is shown that the reaction order with respect to [TiCl.] is closer to one at [I]./[TiC1.]. ≥ 1, and closer to two at [I]./[TiCl.]. >> 1. Considerable kinetic differences were found between conditions using methylcyclohexane or hexane as the nonpolar component of t

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Kinetics and Mechanism of Living Cationic Polymerization of Olefins,tems tend to employ either TiCl. or BCl. coinitiators. Lewis base additives are used to suppress both protic initiation and propagation by free ions. The growing chains are characterized by a reversible ionization equilibrium between a small concentration of active ion pairs and a much larger concen

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