Titlebook: Interaction of Gases with Surfaces; Detailed Description Alexander V. Bogdanov,German V. Dubrovskiy,Victor Book 1995 Springer-Verlag Berli

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Multiphonon Scatteringan analytical expressions for the Debye-Waller exponent (2.1.3) and the correlation function (2.1.4). Replacing the summation over phonon spectrum by integration yields . where . = 3./(2.), . is the Debye temperature, . = . = . is the Debye frequency, . is the sound velocity, . is the Debye wave num

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Microscopic Models of Detailed Kineticsroaches in the statistical theory of equilibrium adsorbates (Flood 1967) and can be considered as mutually complementary ones. Which of them should be used depends on the adsorbate properties (ideal, weakly non-ideal, liquid, polycrystalline, localized, partially localized, delocalized), external co

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Different Regimes of Adsorption Kinetics help of (6.1.16), (7.1.8), (7.1.10) can be rewritten as follows .In dimensionless form the equations (6.1.11), (6.1.19) take on the form . In (8.1.2), (8.1.3) the following dimensionless parameters have been introduced . where . is the relaxation time of a molecule over the variable ., . is the cha

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Equilibrium and Quasiequilibrium Solutions to the LG Modelm cannot be solved in a general form. Therefore let us consider first of all the case of structureless particles, when .(.) should be replaced with .(.) and the condition (8.2.27) is absent. One can readily prove that the quasiequilibrium solution meeting (8.2.24) can be presented in the following w

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Thermodynamical Description of Adsorbed Layer Dynamicsce of the transition probabilities on the coverage (the mean-field approximation) and via direct correlations between elementary processes in different cells. The strict consideration of the problem of lateral interaction may be given by methods of statistical thermodynamics.