Titlebook: Hypervalent Iodine Chemistry; Modern Developments Thomas Wirth Book 2003 Springer-Verlag Berlin Heidelberg 2003 Biochemie.Biochemistry.Ino

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Bildgebende Diagnostik in der Geburtshilfe,ociates with an increase in entropy. Pseudorotation and ligand coupling on iodine(III), and homolytic cleavage of hypervalent iodanes are also discussed. Finally, recent progress in the structural elucidations of λ.-iodanes is shown here.

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https://doi.org/10.1007/978-3-662-49415-8rmation with diaryliodonium salts is then discussed. Finally, the use of sulfonylimino(aryl)iodanes for imidations of phosphorus, sulfur, selenium, and arsenic compounds, including enantioselective transformations (S,Se), and alternate hypervalent iodine approaches to .-sulfonylsulfilimines and N-sulfonylarsinimines are summarized.

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C-C-Bond Forming Reactions,zation of .- and .-substituted phenols, the intramolecular oxidative coupling of phenol ethers, and the reactions of iodonium salts and ylides. A significant recent research activity is centered in the area of the transition metalmediated coupling reactions of the alkenyl-, aryl-, and alkynyliodonium salts.

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Heteroatom-Heteroatom-Bond Forming Reactions,rmation with diaryliodonium salts is then discussed. Finally, the use of sulfonylimino(aryl)iodanes for imidations of phosphorus, sulfur, selenium, and arsenic compounds, including enantioselective transformations (S,Se), and alternate hypervalent iodine approaches to .-sulfonylsulfilimines and N-sulfonylarsinimines are summarized.

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Weiterbildung Gyn?kologie und Geburtshilfeand a variety of transformations of alkynyl(aryl)iodonium salts with heteroatom nucleophiles are then detailed. Finally, the use of sulfonyliminoiodanes as aziridination and amidation reagents, and reactions of iodonium enolates formally derived from monoketones are summarized.

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Oxidations and Rearrangements,gen bonds in the oxidation in carbonyl compounds and the functionalization of only slightly activated carbon-hydrogen bonds in benzylic positions are discussed. New rearrangements using hypervalent iodine compounds are finally mentioned.