Titlebook: Halogen Bonding II; Impact on Materials Pierangelo Metrangolo,Giuseppe Resnati Book 2015 Springer International Publishing Switzerland 201

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Reference work 2021Latest editione reports on the use of elemental iodine in a wide range of organic reactions, the understanding of the actual mode of activation in these cases is very rudimentary. Recently, first proof-of-principle reactions have been established towards the use of carbon-based halogen-bond donors as activators o

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,Characteristics of a σ-Hole and the Nature of a Halogen Bond, and dispersion energies. The importance of induction energy reflects the charge-transfer character of the respective halogen bonds. Intermolecular distances in the second subset are large and the respective contraction of vdW distance upon the formation of a halogen bond is much smaller. Here the d

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Anion Recognition in Solution via Halogen Bonding,d as the basis for multidentate halogen bond donor design. Examples of selective and high-affinity anion recognition through halogen bonding, including implementations in polar, protic media, are discussed.

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Halogen Bonding in Solution,halogen bonds while strongly destabilizes charged, two-center complexes. It does not greatly influence the geometry of three-center halogen bonds, even though polar solvents facilitate dissociation of the counter-ion of charged three-center bonds. The charged three-center bonds are strengthened by i

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Living reference work 2025Latest edition and dispersion energies. The importance of induction energy reflects the charge-transfer character of the respective halogen bonds. Intermolecular distances in the second subset are large and the respective contraction of vdW distance upon the formation of a halogen bond is much smaller. Here the d

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The Palgrave Encyclopedia of Disabilityd as the basis for multidentate halogen bond donor design. Examples of selective and high-affinity anion recognition through halogen bonding, including implementations in polar, protic media, are discussed.

責(zé)問

Living reference work 2025Latest editionhalogen bonds while strongly destabilizes charged, two-center complexes. It does not greatly influence the geometry of three-center halogen bonds, even though polar solvents facilitate dissociation of the counter-ion of charged three-center bonds. The charged three-center bonds are strengthened by i

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Living reference work 2025Latest editionnting the contemporary halogen bonding research, this chapter reviews the solid state structural chemistry of the most extremely polarized halogen atoms, viz. halonium ions, X., and discussed them as halogen bond donors in the solid state [XL.]Y complexes (X=halonium ion, Y=any anion).