Titlebook: Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes; New Developments and Antoine Simonneau Book 2014 Springer Intern

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2190-5053 edented cross-conjugated diketones. In the final part of the research, Simmoneau investigates the gold-catalyzed cycloisomerization mechanism of 1,6-enynes and questions the intermediacy of gold acetylides. By 978-3-319-36097-3978-3-319-06707-0Series ISSN 2190-5053 Series E-ISSN 2190-5061

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Synthesis of Polyconjugated Bis-Enones Through a Gold-Catalyzed 1,3-Acyloxy Migration-Cyclization-1series of elementary steps to fully rearrange the starting material. Before the results being presented and discussed, we will shortly introduce the reactivities accessible from allenyl esters upon gold catalysis and focus on their use in allenyne-type cycloisomerizations.

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Tracking Gold Acetylides in Gold(I)-Catalyzed Cycloisomerization Reactions of 1,6-Enynes,iates have been postulated to intervene in some gold-catalyzed processes involving free alkynes. This study has been conducted as a joint project with mass spectrometry specialists and theoretical chemists.

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