Titlebook: Global Chemical Kinetics of Fossil Fuels; How to Model Maturat Alan K. Burnham Textbook 2017 Springer International Publishing AG 2017 Glob

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Pyrolysis in Open Systems,ical reaction rates are discussed, including limits for heating rates and sample size and geometry that result in the sufficiently accurate temperature measurements. Evidence for sequential versus parallel reaction mechanisms is described, including common misinterpretations in the literature. The c

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Applications to Fossil Fuel Processes, described. The history of reasonable prediction of petroleum generation is reviewed, including how the qualitative models developed in the 1970s were transformed into quantitative models in the 1980s. Differences in geological oil generation temperatures for different kerogen types are shown, as we

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https://doi.org/10.1007/978-3-531-90437-5results are consistent with an effective activation energy of 56–60?kcal/mol, although a higher energy may be appropriate at the low temperatures and higher pressures associated with cracking in the subsurface. The consequences of ignoring isoconversional character are described.

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Sanjit Chatterjee,Palash Sarkar and model fitting methods for deriving chemical kinetic models are described, including how to use simple kinetic analyses to derive initial guesses for nonlinear regression of complex models. Common errors that lead to erroneous Arrhenius parameters are outlined.