Titlebook: Explicitly Correlated Wave Functions in Chemistry and Physics; Theory and Applicati Jacek Rychlewski Book 2003 Springer Science+Business Me

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Progress in Theoretical Chemistry and Physicshttp://image.papertrans.cn/e/image/319364.jpg

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Michael Kleinaltenkamp,Marco Schm?hThe 1/.. singularity in the Hamiltonian describing a system of interacting electrons results in a cusp of the corresponding eigenfunctions. In the vicinity of .. = 0 the non-relativistic wavefunction is linear in .. [1].

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Hylleraas-CI Approach to Diraccoulomb EquationThe 1/.. singularity in the Hamiltonian describing a system of interacting electrons results in a cusp of the corresponding eigenfunctions. In the vicinity of .. = 0 the non-relativistic wavefunction is linear in .. [1].

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Atomic and Molecular Properties Using Explicitly Correlated FunctionsThis chapter presents selected theoretical and numerical results concerning first- and second-order properties of few-electron systems obtained using explicitly correlated wave functions.

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Fragen zum Bilanzrichtlinien-Gesetz,Popular inconsistencies in the concept of electron correlation (in part related to an inappropriate normalization) are clarified. Current claims, e.g. that ‘there is a Fermi correlation between electrons of the same spin, and no correlation between electrons of different spin’, or that the ‘Fermi ho

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https://doi.org/10.1007/978-3-322-91705-8ectronic distance, ... Such functions with the correlation term .. have been proposed for the first time in 1929 by Hylleraas to solve the Schr?dinger equation for helium atom [1]. The Hylleraas wave function can be described as composed of three factors: exponential (Slater type), power expansion o