Titlebook: Electrochemistry of Solids; An Introduction Hans Rickert Book 1982 Springer-Verlag Berlin, Heidelberg 1982 Elektrochemie.Festk?rper.Solids.

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,An Example of Electronic Disorder. Electrons and Electron Defects in α-Ag2S,oncentration change stated above. This means that the thermodynamic behaviour of the electrons in α-Ag.S cannot be understood on the basis of the Boltzmann approximation. It is, however, possible to explain their behaviour quantitatively if the electrons are assumed to be degenerate thus making the

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Book 1982. Since then, the subject of the electro- chemistry of solids has developed further and a large number of new solid electrolytes have been discovered. With the help of solid electrolytes, i. e. solid ionic conductors, galvanic cells are constantly being built for thermodynamic or kinetic investigati

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,E-Government-Strategien für Kommunen,ient. The expressions to be derived are valid for the fluxes of each of the various types of ions and electrons separately. From these expressions the equations for cases in which the transport of various types of particles is interconnected can also be derived; an example is to be found in Chap. 8. Our discussion can be divided into

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Introduction,solid —generally crystalline — compounds in which the electric current is carried by charged atoms, i.e. by ions. The passage of current is thus accompanied by mass transport. The ionic conductivity in solid electrolytes is sometimes as high as that in concentrated liquid electrolytes or molten salt

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Thermodynamic Quantities of Quasi-Free Electrons and Electron Defects in Semiconductors,cuss the thermodynamic quantities of these particles, in particular the electrochemical potential . and the chemical potential ., both considered with respect to a single particle. The electrochemical potential . of the electrons is referred to by semiconductor physicists as Fermi level or Fermi ene

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,An Example of Electronic Disorder. Electrons and Electron Defects in α-Ag2S,able above 179°C; this compound has been studied by Wagner [5.1], Miyatani [5.2], the author, Wedde and Sattler [5.3] and more recently by Bonnecaze, Lichanot and Gromb [5.9]. In 1931, Tubandt and Reinhold [5.4] found that the conductivity of α-silver sulfide being in equilibrium with metallic silve