Titlebook: Electrical Double Layer at a Metal-dilute Electrolyte Solution Interface; G. A. Martynov,R. R. Salem Textbook 1983 Springer-Verlag Berlin

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Physical Principles of the Statistical Theory of the Double Layera to be described satisfactorily, especially at high electrolyte concentrations and electrode potentials, in solvents of low dielectric permittivity, and in the case of multi-charged ions. The situation is even worse with the Stern theory of specific adsorption, which cannot be used in practice for

Oversee

Electrostatic Adsorption in the Gouy Layerlute electrolyte solutions. Here we shall continue to analyse this system and show that it includes two dimensionless parameters: the dimensionless ion charge . and the dimensionless electrode charge .. As the electrolyte concentration decreases, . tends to zero, while . increases. Therefore, in the

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Specific Adsorption in the Stern LayerII) and show that in the presence of specific adsorption forces this system leads to the Stern isotherm (in the preceding chapter we demonstrated that in the absence of these forces the systems leads to the Gouy-Chapman and Wagner-Onsager-Samaras equations). Thus, using system (81), (82), one can co

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crucial

Experimental Dataent on surface tension of a (liquid) electrode σ on the potential ., and also the differential capacity curves C.(.) for a metal-solution interface. Unfortunately, the information carried both by the former and the latter is identical, to a considerable extent. Indeed, it is known from thermodynamic