Titlebook: Di- and Polynuclear Compounds 5; Ulf Thewalt,Reinhard Hemmer Book 1989Latest edition Springer-Verlag Berlin Heidelberg 1989 Titan.polymer.

小卒

Trinuclear Compounds,[π-CH3C(O)C.H.TiBr.].(C.H.O.) is possibly the formula of the reaction product (Formula I) that forms from pentane-1,3,5-triol and π-CH.C(O)C.H.TiBr. in dibutyl ether at 80°C according to a patent [2].

中和

Pentanuclear Compound,(π-C.H.).Ti.S. (Formula I). This cluster compound can be prepared in 73% yield by the reaction between (π-C.H.).Ti(CO). and gaseous H.S (6.4:7.7) in toluene at 80°C for 72 h. It is dark green-brown, moderately air-sensitive and very soluble in toluene. Large crystals are obtained when the toluene solution is layered with hexane [1, 2].

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