Titlebook: Development of a New Heterocycle-Forming Reaction and Kinetic Resolution with N-Heterocyclic Carbene; Yinli Wang Book 2019 Springer Nature

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Enthralling

https://doi.org/10.1007/978-3-662-35216-8les other than NHCs might also induce this transformation. Further investigations showed that a catalytic amount of phosphine or 4-(.-dimethylamino)pyridine (DMAP) also promoted migrative cyclization in an a. Umpolung manner similarly. Furthermore, asymmetric induction was observed when a chiral DMAP derivative was used in the reaction.

WITH

Die Zeit als Tatbestandsmerkmalas fount to give similar results with NHC. The possibility of enantiocontrol of this reaction was indicated by the use of chiral phosphine and binaphthyl-based chiral DMAP. Further investigation on developing an efficient enantioselective variant is currently in progress in this laboratory.

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https://doi.org/10.1007/978-981-13-9398-3Chiral Recognition; N-heterocyclic Carbine; Heterocycle Formation; Kinetic Resolution; Chiral Recognitio

上流社會

syring

合法

neurologist

冷漠

https://doi.org/10.1007/978-3-662-35216-8ompanied 1,2-migration of the sulfonyl groups. This reaction provides a novel access to oxa- and azacycles possessing a pendant vinyl sulfone functionality, which in turn is amenable to further transformations. During research on this migrative cyclization, mechanism studies indicated that nucleophi

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