Titlebook: Development of New Radical Cascades and Multi-Component Reactions; Application to the S Marie-Helene Larraufie Book 2014 Springer Internati

別名

2190-5053 of experimental studies and DFT calculations. The work in this thesis has resulted in numerous publications in high impact journals.The clarity and depth of the experimental section will be useful for students 978-3-319-37786-5978-3-319-01324-4Series ISSN 2190-5053 Series E-ISSN 2190-5061

無脊椎

NAUT

Book 2014es the influence of the chelating effect on Pd(IV) intermediates reactivity with the help of experimental studies and DFT calculations. The work in this thesis has resulted in numerous publications in high impact journals.The clarity and depth of the experimental section will be useful for students

cumber

conduct

Results: Developments of New Radical Cascades with ,-Acylcyanamidesr objectives were to test the reactivity of alkyl, vinyl and aminyl radicals in this process. Indeed, the use of alkyl and vinyl radical should provide us with a straightforward access to natural and biologically active quinazolinones; while the use of aminyl radicals should afford the first radical

進(jìn)步

蚊子

Results: Visible Light-Induced Photoreductive Generation of Radicals from Epoxides and Aziridinesdologies have been reported so far for their radical ring-opening. Epoxides are particularly prone to reductive ring-opening via one-electron transfer. Lithium 4,4′-di-tert-butylbiphenylid (LDBB) has thus been widely used to generate lithiated radical anions such as .. This latter is immediately red

lethal

Supporting Information acetonitrile, DMSO, NEt. and .-BuOH were distilled from CaH.. Thin layer chromatography (TLC) was performed on Merck 60 F254 silica gel. Merck Geduran SI 60 ? silica gel (35?70?mm) was used for column chromatography. The melting points reported were measured with a Reichert hot stage apparatus and

硬化

Gossamer

Supporting Informationphthalene were prepared according to reported procedures. Reactions were carried out with redistilled solvents. THF and Et.O were distilled from sodium/benzophenone. CH.Cl., acetonitrile, NEt. were distilled from CaH.