Titlebook: Desorption Induced by Electronic Transitions DIET V; Proceedings of the F Alan R. Burns,Ellen B. Stechel,Dwight R. Jennison Conference proc

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Reinhold Sellien,Helmut Sellienncident photon energy is raised from 3.9 eV to 6.4 eV, the cross sections for all processes rise exponentially by a factor of 38. Angle resolved measurements with respect to the polar and azimuthal desorption angle show that desorption flux and translational energy carry information about the adsorbate binding geometry prior to desorption.

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Reinhold Sellien,Helmut Sellieneasurements with 300 eV electrons from the bare (water-covered) (1102) surface. Sapphire surfaces were characterized with low energy electron diffraction, reflection electron energy loss spectroscopy, and Auger electron spectroscopy.

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Electron and Photon Stimulated Desorption of Negative Ions from Oriented Physisorbed Moleculesttribute to the rotation of the molecule on the surface during the dissociation process. Photon stimulated desorption of O. ions from O./graphite may also proceed via substrate excitation and photoelectron impact on the adsorbate.

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Charge-Transfer Photodissociation and Photoreaction in Adsorbates at a Metal Surfaceer the total CT photodissociation crosssection is shown to be large by measuring the yield of CH.C1 produced in the reaction of the Cl. with an overlayer of CH.Br. The CH.Br overlayer lowers the work function and so increases the Cl. emission, confirming the CT mechanism.