Titlebook: Crystalline State Photoreactions; Direct Observation o Yuji Ohashi Book 2014 Springer Japan 2014 Crystalline state photoreaction.Excited-st

行為

Racemizations of Alkyl Groups in Cobaloxime Complex Crystals,ng the size and shape of the reaction cavity. For the bulkier (methoxycarbonyl)ethyl groups, not only the inversion of the chiral carbon atom bonded to the cobalt atom but also the .. transformation of the methoxyl group occurs cooperatively. Moreover, solvent molecules in a crystal play an important role in racemization.

嫌惡

Characteristic Processes of Various Racemizations,up. For the 1,2-bis(ethoxycarbonyl)ethyl group, only the two bonds connecting the chiral carbon of the produced radical rotated and opposite side of the radical made a bond to the cobalt atom. Such a two-bond rotation, which is called “hula-twist” as observed in rhodopsin, may be caused by long substituents bonded to the carbon radical.

FACT

Chapter 4: Action and the Pragmatic Maximl group, the . isomerization occurs with retention of the single crystal form. For the 3-butenyl group, the . isomerization does not occur, keeping the single crystal form, although the isomerization occurred in the solid state.

neutrophils

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搬運(yùn)工

貪婪地吃

Book 2014d state reaction, in which a reaction occurs with retention of the single crystal form. The whole reaction processes were observed directly by X-ray and neutron diffractions. In this book, not only the structures of metastable intermediates, such as radicals, carbenes, and nitrenes, but also the uns

CULP

Crystalline-State Reaction and Reaction Cavity, to estimate the void space around the reactive group. For the crystalline-state reaction, it was easy to understand the way how the void space is effectively utilized in the process of the reaction, comparing the void space before and after the reaction.

granite

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