Titlebook: Coordination Chemistry of Macrocyclic Compounds; Gordon A. Melson Book 1979 Plenum Press, New York 1979 Hydrazin.carbon.chemistry.chromium

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978-1-4613-2930-5Plenum Press, New York 1979

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Structural Aspects,macrocycles, which are discussed in Chapters 7 and 8, are excluded. Compounds of the oxygen donor macrocycles, the cyclic polyethers and polycyclic “cryptates,” which are discussed in Chapter 9, are also excluded, except for the two reported structural studies of transition-element derivatives. Only

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Ligand Field Spectra and Magnetic Properties of Synthetic Macrocyclic Complexes,igurations of macrocyclic complexes with transition-metal ions. This chapter reviews those studies that have provided detailed interpretations of the electronic properties of the synthetic macrocyclic complexes. Studies of the naturally occurring macrocycles, e.g., porphyrins or corrins, or the clos

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Chemical Reactivity in Constrained Systems,l to a macrocyclic ligand does introduce constraints on the kind of reaction that can occur. The steric constraints imposed by such binding can affect the electronic structure of the metal, the number and lability of binding sites, the affinity of the metal for other ligands, etc. In many instances

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