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Titlebook: Charge Transfer Reactions in Electrochemical and Chemical Processes; L. I. Krishtalik Book 1986 Consultants Bureau, New York 1986 Atom.Ion

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11#
發(fā)表于 2025-3-23 11:45:43 | 只看該作者
https://doi.org/10.1007/978-3-8348-9234-8ference should be manifested most clearly in proton transfer reactions, since the proton is a particle which behaves essentially in a quantum-mechanical manner.. Therefore, our primary task was to study experimentally an elementary act of proton donor discharge.
12#
發(fā)表于 2025-3-23 14:52:10 | 只看該作者
,Wirtschaftlichkeitsüberlegungen,. The activation energy will be determined by the distance from the minimum of the potential energy surface for the initial state to the saddle point on the line of intersection of this surface with the surface corresponding to the final state. This saddle point is characterized by the coordinates q*, R*, and the energy U*.
13#
發(fā)表于 2025-3-23 21:44:19 | 只看該作者
14#
發(fā)表于 2025-3-24 01:14:59 | 只看該作者
https://doi.org/10.1007/978-3-8348-9234-8 concentration, temperature, etc., one more independent variable, namely the electrode potential, appears in the electrochemical kinetics. This quantity can be varied by polarizing an electrochemical cell with the help of an external power supply.
15#
發(fā)表于 2025-3-24 02:56:14 | 只看該作者
16#
發(fā)表于 2025-3-24 08:35:17 | 只看該作者
The Phenomenological Theory of an Elementary Act, concentration, temperature, etc., one more independent variable, namely the electrode potential, appears in the electrochemical kinetics. This quantity can be varied by polarizing an electrochemical cell with the help of an external power supply.
17#
發(fā)表于 2025-3-24 11:05:42 | 只看該作者
Mechanism of an Elementary Act and the Kinetics of the Cathodic Evolution of Hydrogen,metal and site at which the discharging ion is located. Hence, for different electrolyte solutions with different double-layer structures, the same isotope effect will be observed for identical values of φ - ., where . is the local potential at the site of the discharging ion.
18#
發(fā)表于 2025-3-24 15:33:53 | 只看該作者
The Quantum-mechanical Theory of an Elementary Act,ation of internal energies is required). According to Gurney, the equalization of energies necessary for an electron transfer is attained due to fluctuations of the polar solvent interacting with a charge.
19#
發(fā)表于 2025-3-24 22:05:40 | 只看該作者
20#
發(fā)表于 2025-3-25 00:47:59 | 只看該作者
results of investigations carried out during the last two decades. It is based on the author‘s monograph "Electrode Reactions: The Mechanism of an Elementary Act" (Nauka, 1979). As compared to the first version, the book has been considerably revised and enlarged not only to include a large body of data publi978-1-4684-8720-6978-1-4684-8718-3
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