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Titlebook: Catalytic Oxidations with Hydrogen Peroxide as Oxidant; Giorgio Strukul Book 1992 Springer Science+Business Media Dordrecht 1992 catalysis

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發(fā)表于 2025-3-21 17:25:35 | 只看該作者 |倒序?yàn)g覽 |閱讀模式
書目名稱Catalytic Oxidations with Hydrogen Peroxide as Oxidant
編輯Giorgio Strukul
視頻videohttp://file.papertrans.cn/223/222481/222481.mp4
叢書名稱Catalysis by Metal Complexes
圖書封面Titlebook: Catalytic Oxidations with Hydrogen Peroxide as Oxidant;  Giorgio Strukul Book 1992 Springer Science+Business Media Dordrecht 1992 catalysis
描述Hydrogen peroxide is a chemical that is becoming increasinglyfashionable as an oxidant, both in industry and in academia and whoseproduction is expected to increase significantly in the next fewyears. This growth in interest is largely due to environmentalconsiderations related to the clean nature of hydrogen peroxide as anoxidant, its by-product being only water..To date this chemical has largely been employed as a non-selectiveoxidant in operations like the bleaching of paper, cellulose andtextiles, or in the formulation of detergents, and only to a minimalextent in the manufacture of organic chemicals..This book has been organized to cover the different aspects of thechemistry of hydrogen peroxide. The various chapters into which thebook is divided have been written critically by the authors with thegeneral aim of stimulating new ideas and emphasizing those aspectsthat are likely to lead to new developments in organic synthesis inthe coming future.
出版日期Book 1992
關(guān)鍵詞catalysis; chemistry; hydrogen; organic compounds; water
版次1
doihttps://doi.org/10.1007/978-94-017-0984-2
isbn_softcover978-90-481-4163-0
isbn_ebook978-94-017-0984-2Series ISSN 0920-4652 Series E-ISSN 2215-180X
issn_series 0920-4652
copyrightSpringer Science+Business Media Dordrecht 1992
The information of publication is updating

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發(fā)表于 2025-3-21 21:37:16 | 只看該作者
Hydrogen Peroxide: Manufacture and Industrial Use for Production of Organic Chemicals,ydrogen peroxide began around 1880 [2]. The very diluted hydrogen peroxide produced by the barium peroxide process found only limited use due to high production costs, low hydrogen peroxide content and poor stability.
板凳
發(fā)表于 2025-3-22 03:05:56 | 只看該作者
Activation of Hydrogen Peroxide by Organic Compounds,acts quite slowly with some substrates of interest such as olefins and aromatic hydrocarbons. In order to take advantage of its power, it may be required to “activate” the peroxide functionality. By activation we mean here improving its reactivity toward a substrate through the formation of an inter
地板
發(fā)表于 2025-3-22 08:21:00 | 只看該作者
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發(fā)表于 2025-3-22 09:28:09 | 只看該作者
Activation of Hydrogen Peroxide with Biomimetic Systems,oxisomes are the essential sites of the molecular oxygen uptake by cells. Proteins such as D-aminoacid oxidase, urate oxidase, galactose oxidase, amine oxidases are able to produce hydrogen peroxide in O.-mediated oxidation of the corresponding substrate [1]. In order to control the hydrogen peroxid
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發(fā)表于 2025-3-22 13:53:02 | 只看該作者
Nucleophilic and Electrophilic Catalysis with Transition Metal Complexes,s through which hydrogen peroxide can be employed as primary oxidant for the synthesis of oxygenated compounds. In this chapter it will be discussed how this activation will lead to peroxo complexes having either electrophilic or nucleophilic characteristics and how this guideline may be helpful in
7#
發(fā)表于 2025-3-22 18:27:15 | 只看該作者
Peroxometal Complexes Derived from Hydrogen Peroxide. Some Applications in Organic Synthesis,nd inorganic substrates by hydrogen peroxide[1,2] has been known and synthetically exploited for a long time since the pioneering work of Milas.[3–51 However, only in the last twenty years such a catalytic effect has been satisfactorily rationalized as arising from the . formation of peroxometal spe
8#
發(fā)表于 2025-3-23 00:09:50 | 只看該作者
The Use of Polyoxometalates in Reactions with Hydrogen Peroxide,echanistically complex and often as difficult to control and render selective as metal catalyzed oxidations [1, 2]. The inherent kinetic behavior of oxidants and substrates as well as other factors can give rise to formidable obstacles in this area. A fact of more than passing significance in all or
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發(fā)表于 2025-3-23 03:13:58 | 只看該作者
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發(fā)表于 2025-3-23 06:44:41 | 只看該作者
https://doi.org/10.1007/978-3-031-20740-2eous catalysis to industrial organic chemistry are found. In this field, even for the production of bulk chemicals, homogeneous catalysts appear to compete effectively with heterogeneous ones. This observation is self evident if data taken from the current literature [1] on the world capacity of som
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