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Titlebook: Cage Metal Complexes; Clathrochelates Revi Yan Voloshin,Irina Belaya,Roland Kr?mer Book 2017 Springer International Publishing AG 2017 Cage

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發(fā)表于 2025-3-21 17:07:50 | 只看該作者 |倒序瀏覽 |閱讀模式
書目名稱Cage Metal Complexes
副標題Clathrochelates Revi
編輯Yan Voloshin,Irina Belaya,Roland Kr?mer
視頻videohttp://file.papertrans.cn/221/220745/220745.mp4
概述An exhaustive summary of clathrochelate cage metal complexes and their chemistry, summarizing synthesis and introducing reactivity and applications.Contains over 400 literature references, clearly rep
圖書封面Titlebook: Cage Metal Complexes; Clathrochelates Revi Yan Voloshin,Irina Belaya,Roland Kr?mer Book 2017 Springer International Publishing AG 2017 Cage
描述.This fundamental book presents the most comprehensive summary of the current state in chemistry of cage metal complexes. After their previous book “The Encapsulation Phenomenon” (www.springer.com/978-3-319-27737-0) the authors?in this book?focus on the encapsulation of metal ions by different types of three-dimensional mono- and polynucleating caging ligands. Within these cage metal complexes, (metal) ions can be isolated from external factors...The book provides both a classification of the cage compounds and summaries of synthetic approaches. On that basis the authors then describe the unique chemical and physical properties and the resulting reactivity of the cage compounds, as well as practical and potential applications as potent topological drugs and prodrugs, antifibrillogenic agents, radiodiagnostic and radiotherapeutic compounds, paramagnetic probes, single-molecule magnets, electrocatalysts for hydrogen production, (photo)electronic devices, and many more..Readers will find a well-structured and concise overview, with particular emphasis on a review of synthesis and reactivity of various cage metal complexes, summarizing over 400 literature references, clearly presented
出版日期Book 2017
關鍵詞Cage compounds; Caging ligands; Cation encapsulation; Macrocyclic compounds; Clathrochelates; Paramagneti
版次1
doihttps://doi.org/10.1007/978-3-319-56420-3
isbn_softcover978-3-319-85910-1
isbn_ebook978-3-319-56420-3
copyrightSpringer International Publishing AG 2017
The information of publication is updating

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沙發(fā)
發(fā)表于 2025-3-21 21:27:31 | 只看該作者
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General Considerations,e formation of a complex with an encapsulated metal ion in which (1) a three-dimensional cavity in its macropolycyclic ligand is present, and (2) the metal ion coordinates heteroatoms of this ligand within its cavity, isolating such encapsulated ion from the external factors.
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發(fā)表于 2025-3-22 09:12:05 | 只看該作者
General Considerations,ule(s)] have been provided [1]. They include “(1) the presence of three-dimentional cavity in either covalent, or coordination, or supramolecular caging ligand (capsule) and (2) encapsulation of the above guest anion(s), cation(s) or neutral molecule(s), or their combination within this cavity . for
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發(fā)表于 2025-3-22 15:43:04 | 只看該作者
Synthesis and Reactivity of Cage Metal Complexes,unique or uncommon chemical, physicochemical, and physical properties. Until publication of our first book on clathrochelate chemistry in 2002 [1], main synthetic approaches for preparation of various types of clathrochelates have included:
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發(fā)表于 2025-3-22 20:55:32 | 只看該作者
Practical Applications of Cage Metal Complexes,summarized in this chapter are based on their unprecedented chemical robustness, unusual redox and magnetic properties of an encapsulation metal ion, and three-dimensional shape of these cage molecules as well as on special selectivity of their self-assembly reactions.
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發(fā)表于 2025-3-22 22:01:45 | 只看該作者
Book 2017ectrocatalysts for hydrogen production, (photo)electronic devices, and many more..Readers will find a well-structured and concise overview, with particular emphasis on a review of synthesis and reactivity of various cage metal complexes, summarizing over 400 literature references, clearly presented
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發(fā)表于 2025-3-23 02:18:41 | 只看該作者
will find a well-structured and concise overview, with particular emphasis on a review of synthesis and reactivity of various cage metal complexes, summarizing over 400 literature references, clearly presented 978-3-319-85910-1978-3-319-56420-3
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