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Titlebook: C-H Bond Activation and Catalytic Functionalization I; Pierre H. Dixneuf,Henri Doucet Book 2016 Springer International Publishing Switzerl

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發(fā)表于 2025-3-21 19:54:33 | 只看該作者 |倒序?yàn)g覽 |閱讀模式
書目名稱C-H Bond Activation and Catalytic Functionalization I
編輯Pierre H. Dixneuf,Henri Doucet
視頻videohttp://file.papertrans.cn/221/220080/220080.mp4
概述Overview chapters introduce the newcomer to the topic covered.Series covers hot topics of frontier research summarized by reputed scientists in the field.Volumes are useful and of relevance for a long
叢書名稱Topics in Organometallic Chemistry
圖書封面Titlebook: C-H Bond Activation and Catalytic Functionalization I;  Pierre H. Dixneuf,Henri Doucet Book 2016 Springer International Publishing Switzerl
描述The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.
出版日期Book 2016
關(guān)鍵詞Bond Functinalization; C-C Bond Cross Couplings; C-H Bond Activation; C-H Bond Transformation; C-H Metal
版次1
doihttps://doi.org/10.1007/978-3-319-24630-7
isbn_softcover978-3-319-79649-9
isbn_ebook978-3-319-24630-7Series ISSN 1436-6002 Series E-ISSN 1616-8534
issn_series 1436-6002
copyrightSpringer International Publishing Switzerland 2016
The information of publication is updating

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發(fā)表于 2025-3-21 22:17:01 | 只看該作者
,Rh(III)- and Ir(III)-Catalyzed Direct C–H Bond Transformations to Carbon–Heteroatom Bonds,II) and Ir(III) complexes played an important role to understand the nature of C.H bond activation. While numerous stoichiometric reactions of hydrocarbons with Rh(III) or Ir(III) complexes were scrutinized, their use in catalytic transformations has been relatively undeveloped until recently. Given
板凳
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地板
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5#
發(fā)表于 2025-3-22 11:06:48 | 只看該作者
,New Arylating Agents in Pd-Catalyzed C–H Bond Functionalization of 5-Membered Ring Heteroarenes,–carbon bonds. In most cases, aryl halides were employed as the coupling partners. However, since a few years, several new coupling partners have emerged as useful alternatives for such couplings. This chapter focuses on the recent advances on the discovery of new arylating agents in the palladium-c
6#
發(fā)表于 2025-3-22 13:43:15 | 只看該作者
,Functionalization of [60]Fullerene via Palladium-Catalyzed C–H Bond Activation,terocycles and carbocycles have been obtained. The synthesis of [60]fullerene-fused indolines, isoquinolinones, azepines, tetrahydroisoquinolines, tetrahydrobenzazepines, sultones, tetrahydrobenzooxepines/isochromans, and dihydrophenanthrenes has been achieved by the palladium-catalyzed reactions of
7#
發(fā)表于 2025-3-22 20:01:31 | 只看該作者
,Ruthenium(II)-Catalysed Functionalisation of C–H Bonds with Alkenes: Alkenylation versus Alkylation, heterocycles, alkenes and ferrocene derivatives on their reaction with alkenes, either via oxidative dehydrogenation to produce functional alkenes or via formal insertion of alkene into C–H bonds to afford alkylated products. The regioselectivity of . C–H bond alkenylation or alkylation is shown t
8#
發(fā)表于 2025-3-22 22:44:28 | 只看該作者
,Ruthenium-Catalyzed C?N and C?O Bond-Forming Processes from C?H Bond Functionalization,ynthetic methods for the construction of C?N and C?O bonds through the activation of inert sp. and sp. C?H bonds is enumerated. The effect of a directing group (DG) for the chemo- and regioselective introduction of heteroatoms in the molecule replacing the unactivated C?H bonds is discussed.
9#
發(fā)表于 2025-3-23 01:42:11 | 只看該作者
,,- and ,-Selective C–H Functionalization by C–H Activation,n addition to various strategies for .-selective functionalization via chelation assistance, organometallic C–H activation has recently enabled novel functionalizations of (hetero)arenes at remote .- or .-positions. The .- and .-selectivity was governed either by the inherent substrate structure or
10#
發(fā)表于 2025-3-23 07:52:24 | 只看該作者
,Ruthenium-Catalyzed C?N and C?O Bond-Forming Processes from C?H Bond Functionalization,ynthetic methods for the construction of C?N and C?O bonds through the activation of inert sp. and sp. C?H bonds is enumerated. The effect of a directing group (DG) for the chemo- and regioselective introduction of heteroatoms in the molecule replacing the unactivated C?H bonds is discussed.
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