Titlebook: Boron; The Fifth Element Drahomír Hnyk,Michael McKee Book 2015 Springer International Publishing Switzerland 2015 Boron Chemistry.Boron Che

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Computational Studies of Metallaboranes and Metallacarboranes,Computations based on quantum chemistry, particularly density functional theory methods, have provided valuable insights into the structure, bonding, thermochemistry, and chemical reactivity of diverse polyhedral metallaboranes. Examples of such computations are provided for metallaboranes having central polyhedra with five to 16 vertices.

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Classical and Multicenter Bonding in Boron: Two Faces of Boron,bonding, we usually encounter domination of multicenter bonding. Such examples are planar, quasi-planar, and three dimensional pure and doped boron clusters, two-dimensional sheets as well as conventional deltahedral boranes. However, when a boron atom acquires an extra electron, it tends to form mo

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Molecular Structures of Free Boron Clusters,on diffraction (GED) and/or modern quantum chemical calculations. Such calculations were useful for computing various observables in order to facilitate the analysis of the electron diffraction data. Additionally, microwave spectroscopy was utilized for the two thiaboranes (in conjunction with the U

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Big Borane Assemblies, Macropolyhedral Species and Related Chemistry,le similarly extensive. Molecular chemistry based on boron-hydrides is characterised by cluster formation, and has been dominated by work on single-cluster compounds. For an extensive ‘big molecule’ chemistry based on boron hydrides – one that rivals the extent of chemistry based on carbon hydrides