Titlebook: Biocatalysis; Herfried Griengl Book 2000 Springer-Verlag Wien 2000 Biotechnology.Organische Chemie.biocatalysis.biotechnology/Biokatalyse.

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Psychotropic Drugs and the Perinatal Perioded the corresponding unsaturated ketoalcohol; the residual diol was recovered with a large excess (> 93% ee) of the S configuration. In addition to the enzymatic diene oxidation steps yielding unsaturated diols and ketoalcohols, evidence was also found of enzymatic alkene hydrogenation to yield saturated ketoalcohols and diols.

骨

Immobilization of Rhodococcus AJ270 and Use of Entrapped Biocatalyst for the Production of Acrylic idase activity of the biocatalyst in the hydrolysis of acrylamide. In column reactors, entrapped AJ270 suffers little reduction in amidase activity against 0.25 M acrylamide over 22 h continuous operation.

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Bacterial Biotransformation of Isopreneand Related Dienes,ed the corresponding unsaturated ketoalcohol; the residual diol was recovered with a large excess (> 93% ee) of the S configuration. In addition to the enzymatic diene oxidation steps yielding unsaturated diols and ketoalcohols, evidence was also found of enzymatic alkene hydrogenation to yield saturated ketoalcohols and diols.

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Enantioselective Sulfoxidations Catalyzed by Horseradish Peroxidase, ManganesePeroxidase, and Myelotinuous addition of hydrogen peroxide during turnover and monitoring the presence of native enzyme as well as of intermediates I, II, and III led to the formation of the sulfoxide in high yield (100%) and moderate enantioselectivity (60%, (S)-sulfoxide).

挑剔小責(zé)

Modelling of Enzyme Properties in Organic Solvents, the higher thermostability of enzymes in non-aqueous media. The application of thermodynamics-based models allows first qualitative predictions on the selectivity of many reaction types; however, the application of quantum mechanical/molecular mechanical methods is required for the development of quantitative models of actual reactivity patterns.

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