Titlebook: Advances in Solution Chemistry; I. Bertini,L. Lunazzi,A. Dei Book 1981 Plenum Press, New York 1981 Activation.NMR.Rearrangement.Substituti

EWE

Solute-Solvent Interactions as Required for the Existence of a Liquid,s of the system are decisively influenced by their presence. In liquid water and various other liquids ions are produced by “self-ionization”. In so-called “non aqueous” liquids water is an unavoidable impurity. Solutes and voids are structure-modified and modifying centres (“SMM-centres”) which are

陳舊

倫理學(xué)

Classical Ionic Fluids in the Mean Spherical Approximation,ueous solutions of asymmetric electrolytes. The same approximation has also been used to calculate structure functions of pure and mixed molten salts. The agreement between experimental or “quasi-experimental” structure functions and those obtained within the framework of the MSA is quite good espec

遠(yuǎn)足

A Comparison Between Structures of Aqua and Ammine Complexes in Solutions as Studied by an X-Ray Diuctures of some ethylenediamine complexes were also studied under the same experimental conditions. All of the aqua complexes studied, except the silver(I) complex, have six water molecules in their first hydration sphere. Silver(I) ion has only two water molecules in the linear form. In ammoniacal

過(guò)份

創(chuàng)作

Photo-Induced Ligand-Solvent Interchange in Transition Metal Complexes, orbital and state correlation diagrams reveal the reason for the difference in behavior between d.- and d.-systems. Both for the axially and the equatorially labilized Cr. complexes, it can be shown that the stereomobile reaction is an allowed process, whereas the stereoretent reaction is a forbidd

jumble

Mechanism of Octahedral Substitutions on Transition Metal Complexes. Attempts to Distinguish Betweed to the conclusion that a common five-coordinate intermediate, Co(NH.).., was formed in all these reactions. Recent examinations of different reactions, including KMnO. induced aquation of Co(NH.).(DMSO)., however, suggest different intermediates in different reactions. The mechanism of several oct

繁榮地區(qū)

Use of Electron Paramagnetic Resonance Spectroscopy to Study the Interaction Between Cobalt Schiff xhibiting cobalt and phosphorus hyperfine structure. From analysis of the .P hyperfine tensor, the R-P-R bond angle can be deduced in the phosphine or phosphite, PR.. The calculated spin densities in the cobalt and phosphorus orbitals allows a determination of the relative contributions of σ- and π-

碳水化合物

SKIFF